Multi-scale pore structural change across a paleodepositional transition in Utica shale probed by gas sorption overcondensation and scanning

نویسندگان

چکیده

Pore structure and network configuration in shales greatly impacts physical processes important for hydrocarbon migration, methane extraction, gas storage, or carbon sequestration. The multi-scale nature of the porosity presents significant challenges to its comprehensive accurate characterisation. under-used overcondensation technique can bridge characterisation micropores, below detection limit mercury porosimetry many imaging methods, that macroporosity undetected by conventional adsorption experiments. Further, sorption scanning curves revealed advanced condensation effects allowed probing inter-relation juxtaposition porosities. It was found changeover period, from primarily clay carbonaceous deposits Utica shale, associated with growth disorder pore over particular key length-scales highlighted percolation curves. Critical path theory suggests marked knee developed data at depositional transition would identify a size is characteristic wider network, control mass transport. peak also total organic content accessible shown be dominated phase. Complementary combined computerised X-ray tomography has substantial changes type, super-micron-scale spatial distribution, nanoporosity down approximately 3 nm, mercury, across transition, probably related amount disposition carbonate minerals.

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ژورنال

عنوان ژورنال: Marine and Petroleum Geology

سال: 2021

ISSN: ['0264-8172', '1873-4073']

DOI: https://doi.org/10.1016/j.marpetgeo.2021.105348